Issue 19, 2002

C–Cl/Si–H Exchange catalysed by P,N-chelated Pt(ii) complexes

Abstract

Alkyl chlorides R–Cl are dehalogenated by HSiMe2Ph in the presence of catalytic amounts of the complex [(κ2-P,N)-Ph2PCH2CH2NMe2]PtMeCl to give R–H and ClSiMe2Ph.

Graphical abstract: C–Cl/Si–H Exchange catalysed by P,N-chelated Pt(ii) complexes

Supplementary files

Article information

Article type
Communication
Submitted
05 Jun 2002
Accepted
19 Aug 2002
First published
05 Sep 2002

Chem. Commun., 2002, 2222-2223

C–Cl/Si–H Exchange catalysed by P,N-chelated Pt(II) complexes

F. Stöhr, D. Sturmayr and U. Schubert, Chem. Commun., 2002, 2222 DOI: 10.1039/B205405A

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