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Issue 19, 2002
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C–Cl/Si–H Exchange catalysed by P,N-chelated Pt(II) complexes

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Abstract

Alkyl chlorides R–Cl are dehalogenated by HSiMe2Ph in the presence of catalytic amounts of the complex [(κ2-P,N)-Ph2PCH2CH2NMe2]PtMeCl to give R–H and ClSiMe2Ph.

Graphical abstract: C–Cl/Si–H Exchange catalysed by P,N-chelated Pt(ii) complexes

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Publication details

The article was received on 05 Jun 2002, accepted on 19 Aug 2002 and first published on 05 Sep 2002


Article type: Communication
DOI: 10.1039/B205405A
Chem. Commun., 2002, 2222-2223

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    C–Cl/Si–H Exchange catalysed by P,N-chelated Pt(II) complexes

    F. Stöhr, D. Sturmayr and U. Schubert, Chem. Commun., 2002, 2222
    DOI: 10.1039/B205405A

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