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Issue 11, 2002
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The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids

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Abstract

(±)-Erythro- and (±)-threo- 9,10-difluorostearic acids, which differ only by a stereogenic interconversion of a single C–F bond, have significantly different conformational stabilities.

Graphical abstract: The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids

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Publication details

The article was received on 21 Mar 2002, accepted on 22 Apr 2002 and first published on 07 May 2002


Article type: Communication
DOI: 10.1039/B202891C
Chem. Commun., 2002, 1226-1227

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    The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acids

    M. Tavasli, D. O’Hagan, C. Pearson and M. C. Petty, Chem. Commun., 2002, 1226
    DOI: 10.1039/B202891C

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