Issue 13, 2002

Crystal engineering of metalloporphyrin assemblies. New supramolecular architectures mediated by bipyridylligands

Abstract

Targeted synthesis of new supramolecular motifs of metalloporphyrins in crystals by a concerted mechanism of molecular recognition in three dimensions, aided by organic ligands, is presented; it involves induced assembly of [tetrakis(4-hydroxyphenyl)porphyrinato]zinc species by a combination of axial coordination through bridging bipyridyls and of lateral hydrogen bonding.

Graphical abstract: Crystal engineering of metalloporphyrin assemblies. New supramolecular architectures mediated by bipyridyl ligands

Supplementary files

Article information

Article type
Communication
Submitted
20 Mar 2002
Accepted
24 May 2002
First published
05 Jun 2002

Chem. Commun., 2002, 1420-1421

Crystal engineering of metalloporphyrin assemblies. New supramolecular architectures mediated by bipyridyl ligands

Y. Diskin-Posner, G. K. Patra and I. Goldberg, Chem. Commun., 2002, 1420 DOI: 10.1039/B202791G

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