Issue 11, 2002
From the journal:

Chemical Communications

Highly saddle shaped (porphyrinato)iron(iii) iodide with a pure intermediate spin state

Mikio Nakamura,*ab   Takahisa Ikeue,a   Yoshiki Ohgo,a   Masashi Takahashic  and  Masuo Takedac  

* Corresponding authors

a Department of Chemistry, Toho University School of Medicine, Ota-ku, Tokyo, Japan
E-mail: mnakamu@med.toho-u.ac.jp

b Division of Biomolecular Science, Graduate School of Science, Toho University, Funabashi, Japan

c Department of Chemistry, Faculty of Science, Toho University, Funabashi, Japan

Abstract

Combined analyses using NMR, EPR and Mössbauer spectroscopy as well as SQUID magnetometry have revealed that highly saddle shaped Fe(OETPP)I adopts an essentially pure intermediate spin state in spite of the coordination of an iodide ligand.

Graphical abstract: Highly saddle shaped (porphyrinato)iron(iii) iodide with a pure intermediate spin state

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Article information

DOI
https://doi.org/10.1039/B202768B
Article type
Communication
Submitted
20 Mar 2002
Accepted
22 Apr 2002
First published
02 May 2002

Chem. Commun., 2002, 1198-1199

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Highly saddle shaped (porphyrinato)iron(III) iodide with a pure intermediate spin state

M. Nakamura, T. Ikeue, Y. Ohgo, M. Takahashi and M. Takeda, Chem. Commun., 2002, 1198 DOI: 10.1039/B202768B

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