Issue 13, 2002

From rational octahedron design to reticulation serendipity. A thermally stable rare earth polymeric disulfonate family with CdI2-like structure, bifunctional catalysis and optical properties

Abstract

A new family of lanthanide disulfonates Ln(OH)(NDS)(H2O), (Ln = La, Pr and Nd; NDS=1,5-naphthalenedisulfonate) was designed and hydrothermally synthesized; this is the first example of a disulfonate ligand coordinated to six different Ln atoms; these materials, with high thermal stability, act as active and selective bifunctional catalysts in oxidation and epoxide ring opening; strong luminescence from the optically active Nd center was observed.

Graphical abstract: From rational octahedron design to reticulation serendipity. A thermally stable rare earth polymeric disulfonate family with CdI2-like structure, bifunctional catalysis and optical properties

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2002
Accepted
17 May 2002
First published
05 Jun 2002

Chem. Commun., 2002, 1366-1367

From rational octahedron design to reticulation serendipity. A thermally stable rare earth polymeric disulfonate family with CdI2-like structure, bifunctional catalysis and optical properties

N. Snejko, C. Cascales, B. Gomez-Lor, E. Gutiérrez-Puebla, M. Iglesias, C. Ruiz-Valero and M. A. Monge, Chem. Commun., 2002, 1366 DOI: 10.1039/B202639B

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