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Issue 15, 2002
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The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙, Cu2+ and Gd3+)

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Abstract

A novel heterospin system, [{CuL}2Gd(TCNQ)2]·TCNQ·CH3OH·2CH3CN, is obtained by reacting the mononuclear complex, [CuL], with gadolinium(III) nitrate, followed by the substitution of the nitrato ions with anionic organic radicals.

Graphical abstract: The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙−, Cu2+ and Gd3+)

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Supplementary files

Article information


Submitted
14 Mar 2002
Accepted
07 Jun 2002
First published
28 Jun 2002

Chem. Commun., 2002, 1638-1639
Article type
Communication

The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙, Cu2+ and Gd3+)

A. M. Madalan, H. W. Roesky, M. Andruh, M. Noltemeyer and N. Stanica, Chem. Commun., 2002, 1638
DOI: 10.1039/B202628G

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