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Issue 11, 2002
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Synthesis and characterisation of the first carbene and diazabutadiene–indium(ii) complexes

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Abstract

The reactions of IMes [∶CN(Mes)C2H2N(Mes), Mes = mesityl] and DAB [(ArN[double bond, length as m-dash]CH)2, Ar = C6H3Pri2-2,6] with indium(I) halides have afforded the first carbene and diazabutadiene indium(II) complexes, [In2Br4(IMes)2] and [In2Cl2(DAB˙)2], both of which have been crystallographically characterised.

Graphical abstract: Synthesis and characterisation of the first carbene and diazabutadiene–indium(ii) complexes

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Article information


Submitted
12 Mar 2002
Accepted
18 Apr 2002
First published
01 May 2002

Chem. Commun., 2002, 1196-1197
Article type
Communication

Synthesis and characterisation of the first carbene and diazabutadiene–indium(II) complexes

R. J. Baker, R. D. Farley, C. Jones, M. Kloth and D. M. Murphy, Chem. Commun., 2002, 1196
DOI: 10.1039/B202532A

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