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Issue 9, 2002
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Alkyne coupling in rhenacarbaborane chemistry. Structure of [1,2-μ-NHBut-2,2-(CO)2-3,2-σ:η2-{C([double bond, length as m-dash]CHBut)–CH[double bond, length as m-dash]CHBut}-closo-2,1-ReCB10H9]

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Abstract

The butadienyl moiety in the title compound is bound to both cage-boron and rhenium vertices, and arises from coupling of two alkyne molecules at the rhenium centre, unprecedented in metallacarbaborane chemistry.

Graphical abstract: Alkyne coupling in rhenacarbaborane chemistry. Structure of [1,2-μ-NHBut-2,2-(CO)2-3,2-σ:η2-{C( [[double bond, length as m-dash]] CHBut)–CH [[double bond, length as m-dash]] CHBut}-closo-2,1-ReCB10H9]

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Publication details

The article was received on 18 Feb 2002, accepted on 21 Mar 2002 and first published on 08 Apr 2002


Article type: Communication
DOI: 10.1039/B201772P
Chem. Commun., 2002, 1004-1005

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    Alkyne coupling in rhenacarbaborane chemistry. Structure of [1,2-μ-NHBut-2,2-(CO)2-3,2-σ:η2-{C([double bond, length as m-dash]CHBut)–CH[double bond, length as m-dash]CHBut}-closo-2,1-ReCB10H9]

    S. Du, J. A. Kautz, T. D. McGrath and F. G. A. Stone, Chem. Commun., 2002, 1004
    DOI: 10.1039/B201772P

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