Issue 9, 2002

Alkyne coupling in rhenacarbaborane chemistry. Structure of [1,2-μ-NHBut-2,2-(CO)2-3,2-σ:η2-{C([double bond, length as m-dash]CHBut)–CH[double bond, length as m-dash]CHBut}-closo-2,1-ReCB10H9]

Abstract

The butadienyl moiety in the title compound is bound to both cage-boron and rhenium vertices, and arises from coupling of two alkyne molecules at the rhenium centre, unprecedented in metallacarbaborane chemistry.

Graphical abstract: Alkyne coupling in rhenacarbaborane chemistry. Structure of [1,2-μ-NHBut-2,2-(CO)2-3,2-σ:η2-{C( [[double bond, length as m-dash]] CHBut)–CH [[double bond, length as m-dash]] CHBut}-closo-2,1-ReCB10H9]

Supplementary files

Article information

Article type
Communication
Submitted
18 Feb 2002
Accepted
21 Mar 2002
First published
08 Apr 2002

Chem. Commun., 2002, 1004-1005

Alkyne coupling in rhenacarbaborane chemistry. Structure of [1,2-μ-NHBut-2,2-(CO)2-3,2-σ:η2-{C([double bond, length as m-dash]CHBut)–CH[double bond, length as m-dash]CHBut}-closo-2,1-ReCB10H9]

S. Du, J. A. Kautz, T. D. McGrath and F. G. A. Stone, Chem. Commun., 2002, 1004 DOI: 10.1039/B201772P

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