Issue 11, 2002
From the journal:

Chemical Communications

Synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+cationsvia addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands†

Seung Uk Son,a   Kang Hyun Park,a   Seung Jung Lee,a   Hwimin Seoa  and  Young Keun Chung*a  

* Corresponding authors

a School of Chemistry and Center for Molecular Catalysis, Seoul National University, Seoul, Korea
E-mail: ykchung@plaza.snu.ac.kr

Abstract

The first example of the synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+ cations (3) has been demonstrated by a reaction of (p-cresol)Mn(CO)3+ with KOBut followed by addition of nucleophiles and subsequent quenching with electrophiles in the presence of (S)-binaphthol in CH2Cl2.

Graphical abstract: Synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+ cations via addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands

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Article information

DOI
https://doi.org/10.1039/B201341J
Article type
Communication
Submitted
08 Feb 2002
Accepted
24 Apr 2002
First published
07 May 2002

Chem. Commun., 2002, 1230-1231

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Synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+ cations via addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands

S. U. Son, K. H. Park, S. J. Lee, H. Seo and Y. K. Chung, Chem. Commun., 2002, 1230 DOI: 10.1039/B201341J

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