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Issue 11, 2002
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Synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+cationsvia addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands

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Abstract

The first example of the synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+ cations (3) has been demonstrated by a reaction of (p-cresol)Mn(CO)3+ with KOBut followed by addition of nucleophiles and subsequent quenching with electrophiles in the presence of (S)-binaphthol in CH2Cl2.

Graphical abstract: Synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+ cations via addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands

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Publication details

The article was received on 08 Feb 2002, accepted on 24 Apr 2002 and first published on 07 May 2002


Article type: Communication
DOI: 10.1039/B201341J
Chem. Commun., 2002, 1230-1231

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    Synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3+ cations via addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands

    S. U. Son, K. H. Park, S. J. Lee, H. Seo and Y. K. Chung, Chem. Commun., 2002, 1230
    DOI: 10.1039/B201341J

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