Issue 10, 2002
From the journal:

Chemical Communications

Impact of Pd-mordenite pretreatment on the heterogeneity of Heck catalysis†

M. Dams,a   L. Drijkoningen,a   D. De Vosa  and  P. Jacobs*a  

* Corresponding authors

a Kasteelpark Arenberg 23, Leuven, Belgium
E-mail: pierre.jacobs@agr.kuleuven.ac.be;

Abstract

In Heck reactions with tributylamine as the base and in toluene, Pd(NH3)42+-mordenite (0.4 wt% Pd) and Pd0-mordenite (0.4 and 4 wt% Pd) are not only active and selective, but also truly heterogeneous catalysts, while oxidized PdII species in an all-oxygen environment, i.e. ionic Pd2+ or PdO, are prone to leaching.

Graphical abstract: Impact of Pd-mordenite pretreatment on the heterogeneity of Heck catalysis

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Article information

DOI
https://doi.org/10.1039/B201180H
Article type
Communication
Submitted
31 Jan 2002
Accepted
25 Mar 2002
First published
18 Apr 2002

Chem. Commun., 2002, 1062-1063

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Impact of Pd-mordenite pretreatment on the heterogeneity of Heck catalysis

M. Dams, L. Drijkoningen, D. De Vos and P. Jacobs, Chem. Commun., 2002, 1062 DOI: 10.1039/B201180H

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