Issue 10, 2002
From the journal:

Chemical Communications

Synthesis and crystal structure of a novel pentaconta-nuclear silver anionic cluster complex [HNEt3]4[Ag50S7(SC6H4But-4)40]·2CS2·6C3H6O

Kaluo Tang,a   Xiangjin Xie,a   Yaohua Zhang,a   Xia Zhaoa  and  Xianglin Jin*a  

* Corresponding authors

a Institute of Physical Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, P R China
E-mail: jt1939@pku.edu.cn

Abstract

A silver 4-tert-butylthiophenolate complex generated in situ reacted with CS2 in acetone to give an anionic cluster [Ag50S7(SC6H4But-4)40]4−, the core of which consists of fifty silver atoms and forty-seven sulfur atoms, shaped like a discus with a diameter of ca. 2.0 nm.

Graphical abstract: Synthesis and crystal structure of a novel pentaconta-nuclear silver anionic cluster complex [HNEt3]4[Ag50S7(SC6H4But-4)40]·2CS2·6C3H6O

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Article information

DOI
https://doi.org/10.1039/B201116F
Article type
Communication
Submitted
30 Jan 2002
Accepted
27 Mar 2002
First published
11 Apr 2002

Chem. Commun., 2002, 1024-1025

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Synthesis and crystal structure of a novel pentaconta-nuclear silver anionic cluster complex [HNEt3]4[Ag50S7(SC6H4But-4)40]·2CS2·6C3H6O

K. Tang, X. Xie, Y. Zhang, X. Zhao and X. Jin, Chem. Commun., 2002, 1024 DOI: 10.1039/B201116F

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