Issue 6, 2002
From the journal:

Chemical Communications

Intermolecular recognition and crystal packing in molybdenum and tungsten coordination polymers as deduced from powder X-ray diffraction data†‡

Malcolm H. Chisholm,*a   Paul J. Wilsona  and  Patrick M. Woodward*a  

* Corresponding authors

a Department of Chemistry, The Ohio State University, Newman and Wolfrom Laboratory, 100 W. 18th Avenue, Columbus, USA
E-mail: chisholm@chemistry.ohio-state.edu

Abstract

The molecular conformations and packing of [(tBuCO2)3M2(μ-X)M2(O2CtBu)3], where M = Mo and W, and X = oxalate and perfluoroterephthalate, determined in the solid-state from powder X-ray diffraction analysis, reveal one-dimensional coordination polymers involving pivalate-oxygen to metal interactions (X = perfluoroterephthalate), and oxalate- as well as pivalate-oxygen to metal bonds (X = oxalate), and allows explanation of the unusual state-dependent chromic properties of these compounds.

Graphical abstract: Intermolecular recognition and crystal packing in molybdenum and tungsten coordination polymers as deduced from powder X-ray diffraction data

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Article information

DOI
https://doi.org/10.1039/B200362G
Article type
Communication
Submitted
09 Jan 2002
Accepted
24 Jan 2002
First published
25 Feb 2002

Chem. Commun., 2002, 566-567

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Intermolecular recognition and crystal packing in molybdenum and tungsten coordination polymers as deduced from powder X-ray diffraction data

M. H. Chisholm, P. J. Wilson and P. M. Woodward, Chem. Commun., 2002, 566 DOI: 10.1039/B200362G

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