Issue 10, 2002
From the journal:

Chemical Communications

Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](Agi)22+/(Cuii)24+/(Znii)24+

Dario Braga,*a   Marco Polito,a   Marco Bracaccini,a   Daniela D'Addario,a   Emilio Tagliavini,*a   Davide M. Proserpiob  and  Fabrizia Grepioni*c  

* Corresponding authors

a Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy
E-mail: dbraga@ciam.unibo.it

b Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università di Milano, Via Venezian 21, 20133 Milano, Italy

c Dipartimento di Chimica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy

Abstract

The bidentate sandwich ligand [Fe(η5-C5H4-1-C5H4N)2] has been prepared, structurally characterized and employed in the preparation of the novel supramolecular heterobimetallic metalla-macrocycles [Fe(η5-C5H4-1-C5H4N)2]Ag2(NO3)2·1.5H2O, [Fe(η5-C5H4-1-C5H4N)2]Cu2(CH3COO)4·3H2O and [Fe(η5-C5H4-1-C5H4N)2]Zn2Cl4.

Graphical abstract: Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](Ag)22+/(Cu)24+/(Zn)24+

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Article information

DOI
https://doi.org/10.1039/B200344A
Article type
Communication
Submitted
09 Jan 2002
Accepted
02 Apr 2002
First published
18 Apr 2002

Chem. Commun., 2002, 1080-1081

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Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](AgI)22+/(CuII)24+/(ZnII)24+

D. Braga, M. Polito, M. Bracaccini, D. D'Addario, E. Tagliavini, D. M. Proserpio and F. Grepioni, Chem. Commun., 2002, 1080 DOI: 10.1039/B200344A

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