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Issue 6, 2002
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Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane

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Abstract

The crystal structures of the first U(III) complex of a crown thioether and of its La(III) analog have been determined; a stronger M–S interaction is observed for U(III) with respect to La(III) and Ce(III) in solution and in the solid state.

Graphical abstract: Unique crown thioether complexes of f elements: the crystal structure of U(iii) and La(iii) complexes of 1,4,7-trithiacyclononane

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Publication details

The article was received on 08 Jan 2002, accepted on 08 Feb 2002 and first published on 27 Feb 2002


Article type: Communication
DOI: 10.1039/B200315P
Chem. Commun., 2002, 654-655

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    Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane

    L. Karmazin, M. Mazzanti and J. Pécaut, Chem. Commun., 2002, 654
    DOI: 10.1039/B200315P

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