Issue 6, 2002

Synthesis, structure, and reactions of a nitroxyl complex of iridium(iii), cis,trans-IrHCl2(NH[double bond, length as m-dash]O)(PPh3)2

Abstract

Reaction of Ir(NO)(PPh3)3 with anhydrous HCl results in addition of 2 equivalents of HCl with formal protonation of the nitrosyl ligand, affording the unusual six-co-ordinate nitroxyl complex cis,trans-IrHCl2(NH[double bond, length as m-dash]O)(PPh3)2.

Graphical abstract: Synthesis, structure, and reactions of a nitroxyl complex of iridium(iii), cis,trans-IrHCl2(NH [[double bond, length as m-dash]] O)(PPh3)2

Supplementary files

Article information

Article type
Communication
Submitted
21 Dec 2001
Accepted
06 Feb 2002
First published
27 Feb 2002

Chem. Commun., 2002, 660-661

Synthesis, structure, and reactions of a nitroxyl complex of iridium(III), cis,trans-IrHCl2(NH[double bond, length as m-dash]O)(PPh3)2

R. Melenkivitz and G. L. Hillhouse, Chem. Commun., 2002, 660 DOI: 10.1039/B111645B

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