Issue 7, 2002

Synthesis, structure and magnetism of a new manganese carboxylate cluster: [Mn16O16(OMe)6(OAc)16(MeOH)3(H2O)3]·6H2O

Abstract

A new manganese(III/IV) carboxylate cluster [Mn16O16(OMe)6(OAc)16(MeOH)3(H2O)3]·6H2O has been structurally characterised and shown to display net antiferromagnetic coupling with preliminary evidence for single-molecule magnetic behaviour.

Graphical abstract: Synthesis, structure and magnetism of a new manganese carboxylate cluster: [Mn16O16(OMe)6(OAc)16(MeOH)3(H2O)3]·6H2O

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2001
Accepted
25 Feb 2002
First published
12 Mar 2002

Chem. Commun., 2002, 762-763

Synthesis, structure and magnetism of a new manganese carboxylate cluster: [Mn16O16(OMe)6(OAc)16(MeOH)3(H2O)3]·6H2O

D. J. Price, S. R. Batten, B. Moubaraki and K. S. Murray, Chem. Commun., 2002, 762 DOI: 10.1039/B111404B

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