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Issue 6, 2002
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Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

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Abstract

Treatment of an amido–ytterbium complex with n-BuLi leads to the isolation and structural characterization of a mixed amido–imido–ytterbium or imido–ytterbium complex, respectively, depending upon the molar ratios of the reactants; the Yb–N distance and the linearity of the imido N atom strongly suggest the presence of a formal Yb[double bond, length as m-dash]N multiple bond in these novel complexes.

Graphical abstract: Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

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Article information


Submitted
26 Nov 2001
Accepted
08 Feb 2002
First published
27 Feb 2002

Chem. Commun., 2002, 652-653
Article type
Communication

Synthesis and structural characterization of imido–lanthanide complexes with a metal–nitrogen multiple bond

H. Chan, H. Li and Z. Xie, Chem. Commun., 2002, 652
DOI: 10.1039/B110793C

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