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Issue 4, 2002
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Calixarenes as ligands for transition-metal catalysts: a bis(calix[4]arene-11,23-dicarboxylato) dirhodium complex

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Abstract

A novel dirhodium tetracarboxylate complex is described in which two calix[4]arene macrocycles, bridged at the upper rim by a Rh–Rh unit, serve as ligands and whose solid-state structure shows an unusual coordination of a toluene molecule in the axial position at each rhodium atom.

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Article information


Submitted
16 Nov 2001
Accepted
04 Jan 2002
First published
31 Jan 2002

Chem. Commun., 2002, 338-339
Article type
Communication

Calixarenes as ligands for transition-metal catalysts: a bis(calix[4]arene-11,23-dicarboxylato) dirhodium complex

J. Seitz and G. Maas, Chem. Commun., 2002, 338
DOI: 10.1039/B110478K

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