Issue 1, 2002
From the journal:

Chemical Communications

First example of a covalently bound dimeric inverted porphyrin†

Izabela Schmidta  and  Piotr J. Chmielewski*a  

* Corresponding authors

a Department of Chemistry, University of Wroclaw, F. Joliot-Curie 14, Wroclaw 50 383, Poland
E-mail: pjc@wchuwr.chem.uni.wroc.pl
Fax: (48 071) 32 823 48
Tel: (48 071) 37 57 277

Abstract

Reaction of 5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinatonickel(II) with dihalomethanes in the presence of a proton scavenger gives a 2,21′-CH2-linked dimer of Ni(II) inverted porphyrins with the yield reaching 90% and its 2,2′-linked isomer as a minor product.

Graphical abstract: First example of a covalently bound dimeric inverted porphyrin

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Article information

DOI
https://doi.org/10.1039/B109760C
Article type
Communication
Submitted
25 Oct 2001
Accepted
21 Nov 2001
First published
11 Dec 2001

Chem. Commun., 2002, 92-93

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First example of a covalently bound dimeric inverted porphyrin

I. Schmidt and P. J. Chmielewski, Chem. Commun., 2002, 92 DOI: 10.1039/B109760C

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