Issue 4, 2002
From the journal:

Chemical Communications

Compartmental Schiff-base ligands as selective double-loaded extractants for copper(ii)†

Daniel Black,a   Alexander J. Blake,a   Rachel L. Finn,a   Leonard F. Lindoy,*b   Azizollah Nezhadali,‡b   Gholamhossein Rougnaghi,‡b   Peter A. Tasker*c  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, The University of Nottingham, Nottingham, UK
E-mail: m.schroder@nottingham.ac.uk

b School of Chemistry, University of Sydney, Sydney, N.S.W., Australia 2006

c Department of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK

Abstract

The Robson compartmental macrocyclic ligand derived from the condensation of derivatives of 2,6-diformylphenol and diamines has been prepared for the first time in its free ligand form; competitive three-phase transport and two-phase extraction studies confirm high double-loaded selectivity for the binding and delivery of Cu(II).

Graphical abstract: Compartmental Schiff-base ligands as selective double-loaded extractants for copper(ii)

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Article information

DOI
https://doi.org/10.1039/B109635B
Article type
Communication
Submitted
22 Oct 2001
Accepted
20 Nov 2001
First published
23 Jan 2002

Chem. Commun., 2002, 340-341

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Compartmental Schiff-base ligands as selective double-loaded extractants for copper(II)

D. Black, A. J. Blake, R. L. Finn, L. F. Lindoy, A. Nezhadali, G. Rougnaghi, P. A. Tasker and M. Schröder, Chem. Commun., 2002, 340 DOI: 10.1039/B109635B

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