Jump to main content
Jump to site search

Issue 1, 2002
Previous Article Next Article

First examples of the catalytic asymmetric ring-opening of meso 1,2-dioxines utilising cobalt(II) complexes with optically active tetradentate Schiff base ligands: formation of enantio-enriched cyclopropanes

Author affiliations

Abstract

The combination of chiral cobalt β-ketoiminato or cobalt salen complexes and meso 1,2-dioxines leads to catalytic asymmetric ring-opening affording enantio-enriched cis γ-hydroxy enones; subsequent capture by an ylide affords enantio-enriched cyclopropanes.

Back to tab navigation

Publication details

The article was received on 09 Oct 2001, accepted on 08 Nov 2001 and first published on 14 Dec 2001


Article type: Communication
DOI: 10.1039/B109187P
Chem. Commun., 2002, 28-29

  •   Request permissions

    First examples of the catalytic asymmetric ring-opening of meso 1,2-dioxines utilising cobalt(II) complexes with optically active tetradentate Schiff base ligands: formation of enantio-enriched cyclopropanes

    T. D. Avery, N. F. Jenkins, M. C. Kimber, D. W. Lupton and D. K. Taylor, Chem. Commun., 2002, 28
    DOI: 10.1039/B109187P

Search articles by author

Spotlight

Advertisements