Issue 23, 2001
From the journal:

Chemical Communications

Epoxidation of allylic alcohols in aqueous solutions of non surfactant amphiphilic sugars

Cécile Denis,a   Khalid Misbahi,a   Abdelali Kerbal,b   Vincent Ferrièresa  and  Daniel Plusquellec*a  

* Corresponding authors

a Ecole Nationale Supérieure de Chimie de Rennes, Synthèses et Activations de Biomolécules, CNRS UMR 6052, Institut de Chimie de Rennes, Avenue du Général Leclerc, Rennes, France
E-mail: daniel.plusquellec@ensc-rennes.fr
Fax: (+33 0) 2 99 87 13 98
Tel: (+33 0) 2 99 87 13 01

b Laboratoire de Chimie Organique, Faculté des Sciences, Dhar Elmehrez, Fès, Morocco

Abstract

A variety of cyclic and acyclic allylic alcohols undergo efficient chemo-, regio- and/or stereoselective epoxidations in neutral aqueous solutions of amphiphilic carbohydrates (sucrose, L-arabinose, methyl or ethyl β-D-fructopyranoside) by using dilute hydrogen peroxide in the presence of molybdic or tungstic salts.

Graphical abstract: Epoxidation of allylic alcohols in aqueous solutions of non surfactant amphiphilic sugars

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Article information

DOI
https://doi.org/10.1039/B108352J
Article type
Communication
Submitted
14 Sep 2001
Accepted
15 Oct 2001
First published
15 Nov 2001

Chem. Commun., 2001, 2460-2461

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Epoxidation of allylic alcohols in aqueous solutions of non surfactant amphiphilic sugars

C. Denis, K. Misbahi, A. Kerbal, V. Ferrières and D. Plusquellec, Chem. Commun., 2001, 2460 DOI: 10.1039/B108352J

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