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Issue 24, 2001
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1,2,9,10,17,18,25,26,27,28,35,36,37,38,39,40-Hexadecasila[28](1,2,4,5)-cyclophane and its open-chain homologs

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Abstract

The metathesis of the Si–Si bonds of benzo[1,2∶4,5]-bis(1,1,2,2-tetramethyl-1,2-disilacyclobut-3-ene) with Pd(PPh3)4 gave 1,2,9,10,17,18,25,26,27,28,35,36,37,38,39,40- hexadecasila[28](1,2,4,5)cyclophane and its open-chain homologs, in which the σ–π conjugation is extended all over the molecule.

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Publication details

The article was received on 29 Aug 2001, accepted on 06 Nov 2001 and first published on 06 Dec 2001


Article type: Communication
DOI: 10.1039/B107706F
Chem. Commun., 2001, 2714-2715

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    1,2,9,10,17,18,25,26,27,28,35,36,37,38,39,40-Hexadecasila[28](1,2,4,5)-cyclophane and its open-chain homologs

    S. Kyushin, T. Kitahara, R. Tanaka, M. Takeda, T. Matsumoto and H. Matsumoto, Chem. Commun., 2001, 2714
    DOI: 10.1039/B107706F

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