Issue 20, 2001
From the journal:

Chemical Communications

A new pathway in the reaction of disilene with carbonyl compounds: an ‘ene’ reaction instead of cycloaddition

Vladimir Ya. Lee,a   Masaaki Ichinohea  and  Akira Sekiguchi*a  

* Corresponding authors

a Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki, Japan.
E-mail: sekiguch@staff.chem.tsukuba.ac.jp

Abstract

The 3H-disilagermirene, (tBu2MeSi)4GeSi2, reacts with α-hydrogen containing carbonyl compounds (acetophenone, butane-2,3-dione) by an ‘ene’-reaction pathway followed by isomerization or insertion reactions, representing a new mode in the reaction of disilenes with carbonyl compounds.

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Article information

DOI
https://doi.org/10.1039/B106801F
Article type
Communication
Submitted
26 Jul 2001
Accepted
07 Sep 2001
First published
02 Oct 2001

Chem. Commun., 2001, 2146-2147

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A new pathway in the reaction of disilene with carbonyl compounds: an ‘ene’ reaction instead of cycloaddition

V. Ya. Lee, M. Ichinohe and A. Sekiguchi, Chem. Commun., 2001, 2146 DOI: 10.1039/B106801F

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