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Issue 21, 2001
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Control of methanol oxidation by ionic behavior in supercritical water

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Abstract

In supercritical water the rate of methanol oxidation was controlled by ionic behavior as follows: the oxidation rate of methanol decreased with increasing proton and hydroxide ion concentration, possibly due to stabilization of the reactant, while that of CO was suppressed by added protons and enhanced by added hydroxide ions.

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Article information


Submitted
25 Apr 2001
Accepted
21 Sep 2001
First published
17 Oct 2001

Chem. Commun., 2001, 2270-2271
Article type
Communication

Control of methanol oxidation by ionic behavior in supercritical water

M. Watanabe, K. Sue, T. Adschiri, H. Inomata, R. L. Smith, Jr. and K. Arai, Chem. Commun., 2001, 2270
DOI: 10.1039/B103728P

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