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Issue 17, 2001
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Asymmetric trialkylaluminium addition to aldehydes catalyzed by titanium complexes of N-sulfonylated amino alcohols with two stereogenic centers

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Abstract

The asymmetric methylation, ethylation and allylation of aldehydes using trialkylaluminium reagents catalyzed by titanium(IV) complexes of N-sulfonylated amino alcohols gave excellent enantioselectivities of up to 99% ee.

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Publication details

The article was received on 23 Apr 2001, accepted on 20 Jun 2001 and first published on 01 Aug 2001


Article type: Communication
DOI: 10.1039/B103618C
Chem. Commun., 2001, 1546-1547

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    Asymmetric trialkylaluminium addition to aldehydes catalyzed by titanium complexes of N-sulfonylated amino alcohols with two stereogenic centers

    J. You, S. Hsieh and H. Gau, Chem. Commun., 2001, 1546
    DOI: 10.1039/B103618C

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