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Issue 9, 2001
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{2Fe3S} clusters related to the di-iron sub-site of the H-centre of all-iron hydrogenases

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Abstract

The first synthetic {2Fe3S} clusters structurally related to the sub-site of the H-centre of the all-iron hydrogenases are described: tripodal dithiolate thioether ligands allow the synthesis of di-iron pentacarbonyls with differential (2∶3) S ligation of the Fe atoms.

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Article information


Submitted
08 Mar 2001
Accepted
16 Mar 2001
First published
17 Apr 2001

Chem. Commun., 2001, 847-848
Article type
Communication

{2Fe3S} clusters related to the di-iron sub-site of the H-centre of all-iron hydrogenases

M. Razavet, S. C. Davies, D. L. Hughes and C. J. Pickett, Chem. Commun., 2001, 847
DOI: 10.1039/B102244J

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