Issue 11, 2001
From the journal:

Chemical Communications

Highly enantioselective asymmetric autocatalysis induced by chiral cobalt complexes due to the topology of the coordination of achiral

Itaru Sato,a   Kousuke Kadowaki,a   Yasushi Ohgo,a   Kenso Soai*a  and  Hiroshi Oginob  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, Kagurazaka, Shinjuku-ku, Tokyo, Japan.
E-mail: ksoai@ch.kagu.sut.ac.jp

b Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, Japan

Abstract

Chiral octahedral cobalt complexes, K[Co(edta)]·2H2O and K[Co(trdta)]·2H2O, induce enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the pyrimidyl alkanol with high (85–94%) enantiomeric excesses.

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Article information

DOI
https://doi.org/10.1039/B102143P
Article type
Communication
Submitted
07 Mar 2001
Accepted
25 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 1022-1023

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Highly enantioselective asymmetric autocatalysis induced by chiral cobalt complexes due to the topology of the coordination of achiral ligands

I. Sato, K. Kadowaki, Y. Ohgo, K. Soai and H. Ogino, Chem. Commun., 2001, 1022 DOI: 10.1039/B102143P

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