Issue 12, 2001
From the journal:

Chemical Communications

Synthesis of a 2D polymeric cluster {[NEt4][Mo2O2S6Cu6 I3- (4,4′-bipy)5]·MeOH·H2O} n with a significant improvement of optical limiting effectElectronic supplementary information (ESI) available: preparation, crystal structure details and nonlinear optical measurements for 3. See http://www.rsc.org/suppdata/cc/b1/b101929p/

Qian-Feng Zhang,a   Yunying Niu,a   Wa-Hung Leung,*b   Yinglin Song,c   Ian D. Williamsb  and  Xinquan Xin*a  

* Corresponding authors

a Coordination Chemistry Institute and Department of Chemistry, Nanjing University, Nanjing, P.R. China.
E-mail: xxin@netra.nju.edu.cn

b Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, P.R. China.
E-mail: chleung@ust.hk

c Department of Physics, Harbin Institute of Technology, Harbin, P.R. China

Abstract

The self-assembly reaction of the monomeric nest-shaped cluster [NEt4]2[MoOS3Cu3I3] 1 or twin nest-shaped cluster [NEt4]4[Mo2O2S6Cu 6I6] 2 with the bridging ligand 4,4′-bipyridine (4,4′-bipy) gave a 2D polymeric cluster {[NEt4]- [Mo2O2S6Cu6I3(4,4 ′-bipy)5]·MeOH·H2O} n 3, which exhibits a significant improvement of optical limiting effect in its nonlinear optical properties relative to 1 or 2.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B101929P
Article type
Communication
Submitted
28 Feb 2001
Accepted
03 May 2001
First published
31 May 2001

Chem. Commun., 2001, 1126-1127

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Synthesis of a 2D polymeric cluster {[NEt4][Mo2O2S6Cu6 I3- (4,4′-bipy)5]·MeOH·H2O} n with a significant improvement of optical limiting effect

Q. Zhang, Y. Niu, W. Leung, Y. Song, I. D. Williams and X. Xin, Chem. Commun., 2001, 1126 DOI: 10.1039/B101929P

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