Issue 20, 2001
From the journal:

Chemical Communications

Revision of the absolute configuration of the tricyclic sesquiterpene (+)-kelsoene by chemical correlation and enantiospecific total synthesis of its enantiomer

Sonja Fietz-Razavian,a   Stefan Schulz,*a   Ina Dixa  and  Peter G. Jonesb  

* Corresponding authors

a Institut für Organische Chemie, Technische Universität Braunschweig, Hagenring 30, Braunschweig, Germany.
E-mail: stefan.schulz@tu-bs.de;
Fax: +49 531 391 5272;
Tel: +49 531 391 7353

b Institut für Anorganische Chemie, Technische Universität Braunschweig, Hagenring 30, Braunschweig, Germany

Abstract

The absolute configuration of the recently identified sesquiterpene (+)-kelsoene was revised by chemical correlation with (R)-(+)-pulegone; the correct structure is (1R,2S,5R,6R,7R,8S)- 2,8-dimethyl-6-(1-methylethenyl)tricyclo[5.3.0.02,5]decane.

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Article information

DOI
https://doi.org/10.1039/B101579F
Article type
Communication
Submitted
08 Mar 2001
Accepted
04 Sep 2001
First published
02 Oct 2001

Chem. Commun., 2001, 2154-2155

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Revision of the absolute configuration of the tricyclic sesquiterpene (+)-kelsoene by chemical correlation and enantiospecific total synthesis of its enantiomer

S. Fietz-Razavian, S. Schulz, I. Dix and P. G. Jones, Chem. Commun., 2001, 2154 DOI: 10.1039/B101579F

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