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Issue 8, 2001
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Racemisation and rearrangement of 1,2-dihydro-1,3,5-triazines: a novel reversible thermal electrocyclic reactionElectronic supplementary information (ESI) available: Arrhenius plot for racemisation of enantiomers of 1d. See http://www.rsc.org/suppdata/cc/b1/b101245m/

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Abstract

Chiral 1,2-diaryl-1,2-dihydro-4,6-diamino-1,3,5-triazines undergo facile racemisation by a reversible thermal electrocyclic reaction mechanism; the transient intermediate can lead, after tautomerisation, to rearranged racemic 2-aryl-1,2-dihydro-4-amino-6-anilino-1,3,5-triazines.

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Article information


Submitted
07 Feb 2001
Accepted
08 Mar 2001
First published
30 Mar 2001

Chem. Commun., 2001, 737-738
Article type
Communication

Racemisation and rearrangement of 1,2-dihydro-1,3,5-triazines: a novel reversible thermal electrocyclic reaction

G. Lowe, C. Carr and R. Quarrell, Chem. Commun., 2001, 737
DOI: 10.1039/B101245M

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