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Issue 7, 2001
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Dioxygen mediated oxo-transfer to an amine and oxidative N-dealkylation chemistry with a dinuclear copper complex

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Abstract

Reaction of dioxygen with a dinuclear copper(I) complex of a new binucleating ligand is described, wherein a peroxo–dicopper(II) (Cu2–O2) intermediate leads to an oxo-transfer reaction to give an N-oxide of an N-benzyl internal ligand substrate; additionally observed regioselective oxidative N-dealkylation chemistry occurs.

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Submitted
08 Nov 2000
Accepted
15 Feb 2001
First published
14 Mar 2001

Chem. Commun., 2001, 631-632
Article type
Communication

Dioxygen mediated oxo-transfer to an amine and oxidative N-dealkylation chemistry with a dinuclear copper complex

C. X. Zhang, H. Liang, E. Kim, Q. Gan, Z. Tyeklár, K. Lam, A. L. Rheingold, S. Kaderli, A. D. Zuberbühler and K. D. Karlin, Chem. Commun., 2001, 631
DOI: 10.1039/B009053K

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