1,3-Diphenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphosphetidine: synthesis and structural characterisation of the first nitrogen-penta-coordinated phosphorus with three azide-groups

Christoph Aubauer; Thomas M. Klapötke; Heinrich Nöth; Axel Schulz; Max Suter; Jan Weigand

doi:10.1039/B006944M

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1,3-Diphenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphos phetidine: synthesis and structural characterisation of the first nitrogen-penta-coordinated phosphorus with three azide-groupsElectronic supplementary information (ESI) available: experimental details for 1, Fig. SI 1 and computational details. See http://www.rsc.org/suppdata/cc/b0/b006944m/

Christoph Aubauer,^a Thomas M. Klapötke,*^a Heinrich Nöth,‡^a Axel Schulz,^a Max Suter ‡^a and Jan Weigand^a

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^a Department of Chemistry, Ludwig-Maximilians-University, Butenandtstr. 5-13 (D), Munich, Germany.
E-mail: tmk@cup.uni-muenchen.de

Abstract

(C₆H₅)₂N₂P₂(N₃)₆ 1 has been prepared and characterised by multinuclear NMR, vibrational spectroscopy and single crystal X-ray analysis; the normal modes of 1 have been calculated and the antisymmetric stretching vibration of the azide group has been discussed.

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Article information

DOI: https://doi.org/10.1039/B006944M
Article type: Communication
Submitted: 24 Aug 2000
Accepted: 06 Nov 2000
First published: 30 Nov 2000

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Chem. Commun., 2000, 2491-2492

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1,3-Diphenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphos phetidine: synthesis and structural characterisation of the first nitrogen-penta-coordinated phosphorus with three azide-groups

C. Aubauer, T. M. Klapötke, H. Nöth, A. Schulz, M. Suter and J. Weigand, Chem. Commun., 2000, 2491 DOI: 10.1039/B006944M

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