Issue 22, 2000
From the journal:

Chemical Communications

Rare earth alkoxides as inorganic precursors for olefinpolymerization: an alternative to traditional lanthanocene chemistry

Jérome Gromada,a   Thomas Chenal,a   André Mortreux,*a   Joseph W. Ziller,b   Frédéric Leisingc  and  Jean-François Carpentier*a  

* Corresponding authors

a Laboratoire de Catalyse de Lille, UPRESA CNRS 8010, ENSCL, B.P. 108-59652, Villeneuve d’Ascq Cedex, France.
E-mail: carpentier@ensc-lille.fr

b University of California, Department of Chemistry, Irvine, 92697 CA, USA

c Rhodia Recherches, 52 rue de la Haie Coq 93308, Aubervilliers Cedex, France

Abstract

The combination of the neodymium tert-butoxide [Nd3(μ3-OBut)2(μ-OBu t)3(OBut)4(THF)2] 1 with 1 equivalent of a dialkylmagnesium reagent affords an efficient catalyst for the pseudo-living polymerization of ethylene.

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Article information

DOI
https://doi.org/10.1039/B006941H
Article type
Communication
Submitted
24 Aug 2000
Accepted
02 Oct 2000
First published
23 Oct 2000

Chem. Commun., 2000, 2183-2184

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Rare earth alkoxides as inorganic precursors for olefin polymerization: an alternative to traditional lanthanocene chemistry

J. Gromada, T. Chenal, A. Mortreux, J. W. Ziller, F. Leising and J. Carpentier, Chem. Commun., 2000, 2183 DOI: 10.1039/B006941H

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