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Issue 22, 2000
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Synthesis of benzylcyanoborane adducts of amines and separation of their enantiomers; SN2 substitution at boron atom

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Abstract

Benzylcyanoborane adducts of several amines were prepared in four steps from toluene, their enantiomers were separated using chiral phase HPLC and an SN2 pathway was evidenced in the reaction of a trimethylamine-derived enantiomer with pyridine.

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Publication details

The article was received on 02 Aug 2000, accepted on 02 Oct 2000 and first published on 07 Nov 2000


Article type: Communication
DOI: 10.1039/B006265K
Chem. Commun., 2000, 2275-2276

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    Synthesis of benzylcyanoborane adducts of amines and separation of their enantiomers; SN2 substitution at boron atom

    L. Charoy, A. Valleix, L. Toupet, T. Le Gall, P. Pham van Chuong and C. Mioskowski, Chem. Commun., 2000, 2275
    DOI: 10.1039/B006265K

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