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Issue 21, 2000
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Hydrothermal crystal engineering using hard and soft acids and bases: synthesis and X-ray crystal structures of the metal hydroxide-based phases M3M′2(OH)2[NC5H3(CO2)2-2,4]4(H2O)4 (M = Co, Ni, Zn; M′ = Pd, Pt)

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Abstract

Solvothermal reaction of K2M′Cl4 (M′ = Pd, Pt) with pyridine dicarboxylate and excess base produces isostructural coordination solids in which ‘complex ligands’ containing palladium or platinum coordinate to metal hydroxide chains.

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Publication details

The article was received on 27 Jul 2000, accepted on 20 Sep 2000 and first published on 12 Oct 2000


Article type: Communication
DOI: 10.1039/B006094L
Chem. Commun., 2000, 2107-2108

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    Hydrothermal crystal engineering using hard and soft acids and bases: synthesis and X-ray crystal structures of the metal hydroxide-based phases M3M′2(OH)2[NC5H3 (CO2)2-2,4]4(H2O)4 (M = Co, Ni, Zn; M′ = Pd, Pt)

    L. A. Gerrard and P. T. Wood, Chem. Commun., 2000, 2107
    DOI: 10.1039/B006094L

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