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Issue 20, 2000
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Remarkable cumulative stereoselectivity in cyclopropanation with supramolecular Cu(I) catalytic complexes

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Abstract

Supramolecular Cu(I) catalyst 1 exhibited 77% cumulative (dia- and enantio-) stereoselectivity and one of the highest diastereoselectivities (86% de) obtained to date in the cyclopropanation of styrene with ethyl diazoacetate.

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Publication details

The article was received on 24 Jul 2000, accepted on 30 Aug 2000 and first published on 27 Sep 2000


Article type: Communication
DOI: 10.1039/B006057G
Chem. Commun., 2000, 1993-1994

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    Remarkable cumulative stereoselectivity in cyclopropanation with supramolecular Cu(I) catalytic complexes

    T. Portada, M. Roje, Z. Raza, V. <img border="0" src="https://www.rsc.org/images/entities/char_0043_0306.gif" alt="[C with combining breve]" xmlns="http://www.rsc.org/schema/rscart38" />aplar, M. <img border="0" src="https://www.rsc.org/images/entities/char_005a_0306.gif" alt="[Z with combining breve]" xmlns="http://www.rsc.org/schema/rscart38" />inić and V. <img border="0" src="https://www.rsc.org/images/entities/char_0053_0306.gif" alt="[S with combining breve]" xmlns="http://www.rsc.org/schema/rscart38" />unjić, Chem. Commun., 2000, 1993
    DOI: 10.1039/B006057G

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