A novel acetated 54-member crown-shapedpolyoxomolybdate with unprecedented structural features:Na26[{Na(H2O)2}6({μ3-OH)4MoV20MoVI34O164(μ2-CH3COO)4}]·≈120H2O

Wenbin Yang; Canzhong Lu; Xiang Lin; Honghui Zhuang

doi:10.1039/B004948O

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A novel acetated 54-member crown-shaped polyoxomolybdate with unprecedented structural features: Na₂₆[{Na(H₂O)₂}₆( {μ₃-OH)₄Mo^V₂₀Mo^VI₃₄O₁₆₄(μ₂-CH₃COO) ₄}]·≈120H₂O

Wenbin Yang,^a Canzhong Lu,*^a Xiang Lin^a and Honghui Zhuang^a

Author affiliations

* Corresponding authors

^a The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian, P.R. China.
E-mail: czlu@ms.fjirsm.ac.cn

Abstract

The EPR silent acetated 54-member crown-shaped polyoxomolybdate Na₂₆[{Na(H₂O)₂}₆( {μ₃-OH)₄Mo^V₂₀Mo^VI₃₄- O₁₆₄(μ₂-CH₃COO)₄}] ·≈120H₂O (1), constructed from two different but related building blocks in a new mode, is synthesized in high yield by reducing an acidified aqueous solution of Na₂MoO₄·2H₂O and CH₃COONa·3H₂O.

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Supplementary files

Crystal structure data TXT (58K)

Article information

DOI: https://doi.org/10.1039/B004948O
Article type: Communication
Submitted: 20 Jun 2000
Accepted: 20 Jul 2000
First published: 09 Aug 2000

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Chem. Commun., 2000, 1623-1624

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A novel acetated 54-member crown-shaped polyoxomolybdate with unprecedented structural features: Na₂₆[{Na(H₂O)₂}₆( {μ₃-OH)₄Mo^V₂₀Mo^VI₃₄O₁₆₄(μ₂-CH₃COO) ₄}]·≈120H₂O

W. Yang, C. Lu, X. Lin and H. Zhuang, Chem. Commun., 2000, 1623 DOI: 10.1039/B004948O

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