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Issue 17, 2000
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Alcohol induced stereospecific P–C bond cleavage to afford Ru–phenyl derivatives containing three different types of stereogenicity: novel and unprecedented complexes of P(OH)(OR)Ph

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Abstract

Alcohol induced stereospecific P–C bond cleavage in a Ru–P(OH)Ph2 fragment affords new chiral-Binap and MeO-Biphep based complexes containing three different forms of stereogenicity: ligand atropisomerism plus stereogenic Ru and P atoms; these represent the first reported transition metal complexes of the ligands P(OH)(OR)Ph.

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Publication details

The article was received on 31 May 2000, accepted on 19 Jul 2000 and first published on 10 Aug 2000


Article type: Communication
DOI: 10.1039/B004385K
Chem. Commun., 2000, 1629-1630

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    Alcohol induced stereospecific P–C bond cleavage to afford Ru–phenyl derivatives containing three different types of stereogenicity: novel and unprecedented complexes of P(OH)(OR)Ph

    T. J. Geldbach, D. Drago and P. S. Pregosin, Chem. Commun., 2000, 1629
    DOI: 10.1039/B004385K

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