Novel layer-type triple salts of silver(i), AgCN·AgF·4AgCF3CO2·2L (L = MeCN or H2O)Dedicated to the memory of Professor George Alan Jeffrey (1915–2000).
Abstract
The novel silver(I) triple salts AgCN·AgF·4AgCF3CO2·2L (L = MeCN or 2H2O) exhibit the same type of layer structure, in which [F@Ag6] units each representing a fluoride-centred octahedral silver cage are interconnected by μ4-κC,κC∶κN ,κN-cyanide and μ4-O,O∶O′,O ′-trifluoroacetato bridges.