Issue 15, 2000

Novel layer-type triple salts of silver(i), AgCN·AgF·4AgCF3CO2·2L (L = MeCN or H2O)Dedicated to the memory of Professor George Alan Jeffrey (1915–2000).

Abstract

The novel silver(I) triple salts AgCN·AgF·4AgCF3CO2·2L (L = MeCN or 2H2O) exhibit the same type of layer structure, in which [F@Ag6] units each representing a fluoride-centred octahedral silver cage are interconnected by μ4CC∶κN N-cyanide and μ4-O,O∶O′,O ′-trifluoroacetato bridges.

Supplementary files

Article information

Article type
Communication
Submitted
12 May 2000
Accepted
19 Jun 2000
First published
12 Jul 2000

Chem. Commun., 2000, 1435-1436

Novel layer-type triple salts of silver(I), AgCN·AgF·4AgCF3CO2·2L (L = MeCN or H2O)

Q. Wang and T. C. W. Mak, Chem. Commun., 2000, 1435 DOI: 10.1039/B003821K

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