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Issue 13, 2000
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A versatile approach to the total synthesis of the pseudomonic acids

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Abstract

The total synthesis of pseudomonic acid C is described using an approach which gives access to analogues and putative biosynthetic precursors; the key step is installation of the C7 side-chain via alkylation of a trisubstituted δ-lactone with complete stereocontrol and in 85% yield under conditions which avoid the possible competing elimination of a protected hydroxy group β to the carbonyl.

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Article information


Submitted
17 Apr 2000
Accepted
12 May 2000
First published
08 Jun 2000

Chem. Commun., 2000, 1109-1110
Article type
Communication

A versatile approach to the total synthesis of the pseudomonic acids

C. Mckay, T. J. Simpson, C. L. Willis, A. K. Forrest and P. J. O’Hanlon, Chem. Commun., 2000, 1109
DOI: 10.1039/B003094P

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