Issue 11, 2000

Palladium catalysed cyclisation-Barbier-type allylation cascades

Abstract

Pd(0) catalysed termolecular queuing processes involving cyclisation of aryl halides onto proximate alkynes, allene (1 bar) insertion, transmetallation of the resulting π-allylpalladium(II) species with indium and addition to an aldehyde affords heterocyclic and carbocyclic dienes.

Article information

Article type
Communication
Submitted
05 Apr 2000
Accepted
18 Apr 2000
First published
16 May 2000

Chem. Commun., 2000, 933-934

Palladium catalysed cyclisation-Barbier-type allylation cascades

U. Anwar, R. Grigg and V. Sridharan, Chem. Commun., 2000, 933 DOI: 10.1039/B002713H

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