Enhanced mobility of the cluster Ru3(CO)12 in the solid state formed in situ by the reaction of CO and Ru3(CO)6(μ-CO)(μ3∶η2∶η3∶η5-C12H8) on silica

Silvio Aime; Alejandro Arce; Roberto Gobetto; Daniela Giusti; Marc Stchedroff

doi:10.1039/B002641G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Enhanced mobility of the cluster Ru₃(CO)₁₂ in the solid state formed in situ by the reaction of CO and Ru₃(CO)₆(μ-CO)(μ₃∶η²∶η³∶η⁵-C₁₂H ₈) on silica

Silvio Aime,*^a Alejandro Arce,^b Roberto Gobetto,^a Daniela Giusti^a and Marc Stchedroff^a

Author affiliations

* Corresponding authors

^a Dipartimento di Chimica Inorganica, Chimica Fisica dei Materiali, Università degli Studi di Torino, via Pietro Giuria 7, Torino, Italy.
E-mail: aime@ch.unito.it

^b Centro de Quimica, Instituto Venezolano de Investigaciones Cientificas (IVIC), Apartado 21827, Caracas, Venezuela

Abstract

The reaction of Ru₃(CO)₆(μ-CO)(μ₃∶η²∶η³∶η⁵-C₁₂H ₈) (physisorbed on SiO₂) with CO in the solid state leads to Ru₃(CO)₁₂ and acenaphthylene in quantitative yields; the Ru₃(CO)₁₂ generated in situ is highly mobile leading to a reduced chemical shielding anisotropy.

Download options Please wait...

Article information

DOI: https://doi.org/10.1039/B002641G
Article type: Communication
Submitted: 28 Mar 2000
Accepted: 20 Jun 2000
First published: 11 Jul 2000

Download Citation

Chem. Commun., 2000, 1425-1426

Permissions

Request permissions

Enhanced mobility of the cluster Ru₃(CO)₁₂ in the solid state formed in situ by the reaction of CO and Ru₃(CO)₆(μ-CO)(μ₃∶η²∶η³∶η⁵-C₁₂H ₈) on silica

S. Aime, A. Arce, R. Gobetto, D. Giusti and M. Stchedroff, Chem. Commun., 2000, 1425 DOI: 10.1039/B002641G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications