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Issue 8, 2000
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Bis(pentafluorophenyl)boron azide: synthesis and structural characterization of the first dimeric boron azide

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Abstract

The reaction of (C6F5)2BCl with trimethylsilyl azide results in the formation of (C6F5)2BN3 1; evaporation of the stabilizing solvent results in irreversible dimerization yielding [(C6F5)2BN3]2 1a as the first example of a dimeric boron azide; in the presence of pyridine a stable adduct (C6F5)2BN3·py 2 is isolated.

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Article information


Submitted
09 Feb 2000
Accepted
06 Mar 2000
First published
03 Apr 2000

Chem. Commun., 2000, 667-668
Article type
Communication

Bis(pentafluorophenyl)boron azide: synthesis and structural characterization of the first dimeric boron azide

W. Fraenk, T. M. Klapötke, B. Krumm and P. Mayer, Chem. Commun., 2000, 667
DOI: 10.1039/B001103G

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