A mixed-metal CuII2NiII2 complex derived from a phenol-based heterotetranucleating macrocyclic ligand

Masami Yonemura; Hisashi Ōkawa; Masaaki Ohba; David E. Fenton; Laurence K. Thompson

doi:10.1039/B000516I

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A mixed-metal Cu^II₂Ni^II₂ complex derived from a phenol-based heterotetranucleating macrocyclic ligand

Masami Yonemura,^a Hisashi Ōkawa,*^a Masaaki Ohba,^a David E. Fenton^b and Laurence K. Thompson^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashiku, Fukuoka, Japan.
E-mail: okawascc@mbox.nc.kyushu-u.ac.jp

^b Department of Chemistry, The University of Sheffield, Sheffield, UK

^c Department of Chemistry, Memorial University of Newfoundland, St. John’s, Newfoundland, Canada

Abstract

A new phenol-based tetranucleating macrocycle, having two N(amine)₂O₂ and two N(imine)₂O₂ metal-binding sites in the macrocyclic framework, forms a Cu^II₂Ni^II₂ complex of a defective double-cubane structure.

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Supplementary files

Crystal data TXT (37K)

Article information

DOI: https://doi.org/10.1039/B000516I
Article type: Communication
Submitted: 17 Jan 2000
Accepted: 03 Apr 2000
First published: 25 Apr 2000

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Chem. Commun., 2000, 817-818

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A mixed-metal Cu^II₂Ni^II₂ complex derived from a phenol-based heterotetranucleating macrocyclic ligand

M. Yonemura, H. Ōkawa, M. Ohba, D. E. Fenton and L. K. Thompson, Chem. Commun., 2000, 817 DOI: 10.1039/B000516I

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Chemical Communications

A mixed-metal Cu^II₂Ni^II₂ complex derived from a phenol-based heterotetranucleating macrocyclic ligand

Abstract

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A mixed-metal Cu^II₂Ni^II₂ complex derived from a phenol-based heterotetranucleating macrocyclic ligand

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