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Issue 5, 2000
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High turnover number of γ-SiW10{MnIII(OH2)}2 O386− for oxygenation of cyclohexane with 1 atm molecular oxygenElectronic supplementary information (ESI) available: preparation and characterization of polyoxometalates. See http://www.rsc.org/suppdata/cc/a9/a910334l/

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Abstract

An all-inorganic oxo-bridged dimanganese-containing silicotungstate, γ-SiW10{MnIII(OH2)}2 O386−, showed the highest turnover number of 789 among various metal-substituted silicotungstates for the oxygenation of cyclohexane with 1 atm molecular oxygen; this is the highest level when compared with other catalysts reported so far.

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Supplementary files

Article information


Submitted
24 Dec 1999
Accepted
03 Feb 2000
First published
24 Feb 2000

Chem. Commun., 2000, 381-382
Article type
Communication

High turnover number of γ-SiW10{MnIII(OH2)}2 O386− for oxygenation of cyclohexane with 1 atm molecular oxygen

T. Hayashi, A. Kishida and N. Mizuno, Chem. Commun., 2000, 381
DOI: 10.1039/A910334L

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