Issue 7, 2000
From the journal:

Chemical Communications

The dinuclear manganese complex Mn2O(OAc)2(TPTN) as a catalyst for epoxidations with hydrogen peroxideAbbreviations TPTN = N,N,N′,N′-tetrakis(2-pyridylmethyl)propane-1 ,3-diamine, TPEN = N,N,N′,N′-tetrakis(2-pyridylmethyl)ethane-1, 2-diamine.

Jelle Brinksma,a   Ronald Hage,b   Judith Kerschnerc  and  Ben L. Feringa*a  

* Corresponding authors

a Laboratory of Organic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
E-mail: B.L.Feringa@chem.rug.nl

b Unilever Research Laboratory Vlaardingen, PO Box 114, 3130 AC, Vlaardingen, The Netherlands

c Unilever Research US, 45 River Road, Edgewater, New Jersey 07020, USA

Abstract

In acetone and at ambient temperature, the dinuclear manganese complex of TPTN is able to catalyse the oxidation of several alkenes to the corresponding epoxides with high turnovers numbers (up to 900) using H2O2 as oxidant.

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Article information

DOI
https://doi.org/10.1039/A910232I
Article type
Communication
Submitted
17 Dec 1999
Accepted
24 Feb 2000
First published
15 Mar 2000

Chem. Commun., 2000, 537-538

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The dinuclear manganese complex Mn2O(OAc)2(TPTN) as a catalyst for epoxidations with hydrogen peroxide

J. Brinksma, R. Hage, J. Kerschner and B. L. Feringa, Chem. Commun., 2000, 537 DOI: 10.1039/A910232I

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