SCHEDULED MAINTENANCE
A tris(alkoxy)benzylamine (BAL) handle strategy was developed for safety-catch anchoring of D-glucosamine derivatives in solid-phase synthesis of oligosaccharides; the linkage between the BAL handle and the amine proved stable to conc. TFA and Lewis acids, but after N-acylation the amide could be released by treatment with TFA–H2O (19∶1).
J. F. Tolborg and K. J. Jensen, Chem. Commun., 2000, 147 DOI: 10.1039/A908446K
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