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Issue 23, 1999
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Bispyrene based chiroptical molecular redox switch

Abstract

The chiral trans-cyclohexanediol bispyrene esters (1R,2R)-1a and (1S,2S)-1b are reversibly reduced to the corresponding bisradical anions 1a2– and 1b2– which show strong absorption bands at 510 nm exhibiting exciton-split circular dichroism (CD) with opposite signs, whereas the radical anions of the bisamides 2a and 2b failed to show split CD signals.

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Article information


Chem. Commun., 1999, 2427-2428
Article type
Paper

Bispyrene based chiroptical molecular redox switch

C. Westermeier, H. Gallmeier, M. Komma and J. Daub, Chem. Commun., 1999, 2427
DOI: 10.1039/A907454F

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