Jump to main content
Jump to site search

Issue 23, 1999
Previous Article Next Article

Synthesis of an anionic tridentate phosphinoborate and its reaction chemistry with Sn(II)

Abstract

Dichlorophenylborane reacts smoothly with [Li- (tmen)][CH2PPh2] in THF to afford, in good yields, the Li(tmen)+ salt of a novel monoanionic tridentate phosphinoborate, tris(diphenylphosphinomethyl)phenylborate; reaction of the ligand with SnCl2 produces tris(diphenylphosphinomethyl) phenylboratotin(II) chloride, which may be dehalogenated to give the η3 compound, {[PhB- (CH2PPh2)3]Sn}PF6, tris(diphenylphosphinomethyl)- phenylboratotin(II) hexafluorophosphate.

Back to tab navigation

Article information


Chem. Commun., 1999, 2379-2380
Article type
Paper

Synthesis of an anionic tridentate phosphinoborate and its reaction chemistry with Sn(II)

A. A. Barney, A. F. Heyduk and D. G. Nocera, Chem. Commun., 1999, 2379
DOI: 10.1039/A906560A

Social activity

Search articles by author

Spotlight

Advertisements